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0225
1、与结构基元相对应的是西南大学网院答案请咨询微信或QQ515224986
素向量
晶胞
复格子
点阵点
参考答案：点阵点；
2、杂化轨道是
两个原子的原子轨道线性组合形成一组新的原子轨道
一个原子的不同类型的原子轨道线性组合形成一组新的原子轨道
两个分子的分子轨道线性组合形成一组新的分子轨道
两个原子的原子轨道线性组合形成一组新的分子轨道
参考答案：一个原子的不同类型的原子轨道线性组合形成一组新的原子轨道；
3、晶体等于
F.结构基元+点阵
特征对称要素+结构基元
晶胞+点阵
特征对称要素+点阵
参考答案：F.结构基元+点阵；
4、若用电子束与中子束分别作衍射实验，得到大小相同的环纹，则说明二者
A.动能相同
动量相同
速度相同
质量相同
5、下列分子具有偶极矩，而不属于Cnv群的是
H2C=CH2
CH2Cl2
NH3
H2O2
6、杂化轨道不必满足下列哪一条性质
E.杂化轨道必须是正交归一的
每个轨道在杂化前后总成分保持不变
杂化轨道必然是简并的轨道
轨道杂化前后数目必须守恒
7、Li原子的3个电离能分别为I1=5.392eV,I2=75.638eV,I3=122.451eV。则Li原子1s电子的结合能是：
-138.17eV
-75.64eV
-65.3eV
-203.48eV
8、离子晶体中，负离子在正离子周围形成配位多面体。根据正负离子的半径比，可以判断正离子的配位数与配位多面体型式。下列判断正确的是：
r+/r-=0.2正离子配位多面体为四面体
r+/r-=0.3正离子配位多面体为三角形
r+/r-=0.4正离子配位多面体为立方体
r+/r-=0.5正离子配位多面体为八面体
9、考虑到电子的自旋，氢原子n=3的微观运动状态有多少种：
3
6
9
18
10、对于一维势箱中的粒子，下列说法错误的是：
体系的基态能量为零
波函数的节点数为n-1
粒子在箱中动量的平均值为零
粒子在箱中的运动满足不确定关系
11、提出实物粒子也有波粒二象性学的科学家是：
德布罗意
爱因斯坦
海森堡
狄拉克
12、分子轨道是
原子轨道的线性组合
分子中所有电子空间运动的状态函数
分子中单电子运动的完全波函数
分子中电子空间运动的轨道
13、根据宏观对称要素知道某晶体属D2d点群，由此判断此晶体属于()晶系
D.立方
正交
单斜
四方
14、Pauli原理的正确叙述为
C.原子中每个电子的运动状态必须用四个量子数来描述
同一原子中不可能有四个量子数完全相同的两个电子
每个自旋-轨道最多只能容纳自旋方向相反的两个电子
电子体系的空间波函数对于交换电子必须是反对称的
15、分子的三重态意味着分子中
B.有三对未成对电子
有两个自旋相同的未成对电子
有一个未成对电子
有两个自旋相反的未成对电子
16、O2的键长小于O2<sup>?</sup>的键长
A.√
B.×
17、凡是成键轨道都具有中心对称性
A.√
B.×
18、通过解氢原子的薛定谔方程，可得到<em>n，l，m</em>和<em>ms</em>四个量子数
A.√
B.×
19、用HMO法处理共轭分子时，其久期行列式中，主对角线上积分元的数值为，与主对角线上的相连的积分元数值为，其他的积分元为零
A.√
B.×
20、立方最密堆积型金属和六方最密堆积金属的堆积系数相等，晶胞内原子数、八面体空隙数、四面体空隙数的比值均为1:1:2
A.√
B.×
21、氢原子的2p轨道能级比2s轨道能级高
A.√
B.×
22、正当格子一定是素格子
A.√
B.×
23、电子自旋量子数<em>s</em>=±1/2
A.√
B.×
24、中心原子采用dsp<sup>2</sup>杂化方式，其空间构型为四面体
A.√
B.×
25、立方晶系的空间点阵形式有cP,cI,cF与cR。
A.√
B.×
26、晶体中对称轴的轴次只能是1,2,3,4,6。
A.√
B.×
27、甲烷分子有对称中心。
A.√
B.×
28、仅由非极性键构成的分子不一定是非极性分子
A.√
B.×
29、<imgsrc="http://zuoye.eduwest.com/resourcefile/uploadFiles/file/questionImgs/201609151473898663126032170.png"title="201609151473898663126032170.png"alt="blob.png"/>
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31、<imgsrc="http://zuoye.eduwest.com/resourcefile/uploadFiles/file/questionImgs/201609151473899526479052371.png"title="201609151473899526479052371.png"alt="blob.png"/>
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35、<imgsrc="http://zuoye.eduwest.com/resourcefile/uploadFiles/file/questionImgs/201609151473899131099032054.png"title="201609151473899131099032054.png"alt="blob.png"/>
36、<imgsrc="http://zuoye.eduwest.com/resourcefile/uploadFiles/file/questionImgs/201609151473899579465012177.png"title="201609151473899579465012177.png"alt="blob.png"/>
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38、<imgsrc="http://zuoye.eduwest.com/resourcefile/uploadFiles/file/questionImgs/201609151473898974189018983.png"title="201609151473898974189018983.png"alt="blob.png"/>
39、按分子轨道理论写出NF，NF<sup>+</sup>，NF<sup>?</sup>基态时的电子组态，说明他们的不成对电子数和磁性（提示：按照类似O2的能级排）
40、<imgsrc="http://zuoye.eduwest.com/resourcefile/uploadFiles/file/questionImgs/201609151473899034513065679.png"title="201609151473899034513065679.png"alt="blob.png"/>
41、在极性分子AB中的一个分子轨道上运动的电子，在A原子的f</em>A原子轨道上出现的概率为80%，B原子的f</em>B原子轨道上出现的概率为20%，写出该分子轨道波函数。
42、写出N2基态时的价层电子组态，并解N2的键长(109.8pm)特别短、键能(942kJ·mol<sup>-1</sup>)特别大的原因。
43、
44、写出NF<sup>+</sup>的价电子组态、键级和磁性。
45、
46、<imgwidth="554"height="42"src="data:image/png;base64,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"/>
47、链型共轭分子<imgwidth="197"height="23"src="data:image/png;base64,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"/>的长波方向460nm处出现第一个强吸收峰，试按一维势模型估算其长度。
48、<imgwidth="554"height="42"src="data:image/png;base64,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"/>
49、在LCAO-MO方法中，各原子轨道对分子轨道的贡献可由哪个决定：-----------------()(A)组合系数ij(B)(ij)2</sup>(C)(ij)1/2</sup>(D)(ij)-1/2(B)
50、请通过计算说明，用氢原子从第六激发态跃到基态所产生的光子照射长度为1120pm的线型分子H2CCHCHCHCHCHCH2，该分子能否产生吸收光谱？若能，计算谱线的最长波长；若不能，请提出将不能变为可能的思路。
51、写出CN-</sup>的价电子组态及键级
52、什么叫分子轨道？按量子力学基本原理做了哪些近似以后才有分子轨道的概念？这些近似的根据是什么？
53、<imgwidth="554"height="42"src="data:image/png;base64,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"/>
54、对于氢原子：（a）分别计算从第一激发态和第六激发态跃迁到基态所产生的光谱线的波长，说明这些谱线所属的线系及所处的光谱范围。（b）上述两谱线产生的光子能否使：（i）处于基态的另一氢原子电离？（ii）金属铜中的原子电离？（铜的功函数(c)若上述两谱线所产生的光子能使铜晶体的电子电离，请计算从铜晶体表面射出的光电子的德布罗意波的波长
55、<imgwidth="554"height="83"src="data:image/png;base64,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"/>
56、试述由原子轨道有效地形成分子轨道的条件。
57、<imgwidth="554"height="104"src="data:image/png;base64,R0lGODlhKgJoAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALAEABQApAkkAhgAAAAAAAB0AHQAAHR0AAB0dABwcHAAdHR0AMgAAMwAdMh0dNAAcSB0dSB00NAAyMgAzWh0zWgA0SB4zRx1IWx1JSR1GbDMAADIAHTIdADIAMjQdNDMeRzIyADQ0HTQ0NDMzWzMzSDNdXTNGRjNGbjVbbjNbgEgcAEgdHUceM1ozAFozHUczHkg0AFszM0gzM0YzRltIHUlJHVtINUZGM11dM1tISFtbW0hIW0ZGRl1dbkhZf0ZGbllZf1l/WVtuSEhuW0huf11/f1luf1l/bkRubllubmxGHW5GM25bNW5dXX9ZSH9ZWW5GRm5bSH9uSH9/XX9uWW5uWW5/WW5uRGpqam5ugG6AbmaIiIBbM4BuboiIZgECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwECAwf/gAAAAkGChgGGggEBEIZZi4mRkpOUlZaXmJmam5ydnp+goaKjpKWmp6ipqquslAEDkRYAR4YggheSBK27vL2+v8DBwsPExcakhYIIhhqRKpMMx9LT1NXW19jZ2qQYidGCJyaGtNDb5ufo6err7NnJAI3ghieMk7Lt+Pn6+/z96N2CyMlLROCeIQ7+EipcyLChw0zvvgE4EUmgIBcPM2rcyLHjNIDKDC2LFG+Wx5MoU6pcqendM0EGBaFwRJOlzZs4c+ojAGlePUWvxi1alECn0aNIkypdyrSp06dQo0qdSrWq1atYs2rdyrWr169gw4odS7as2bNo06pdy7at27dw/+PKnUu3rt27ePPq3cu3r9+/gAMLHky4sOHDiBMrXsy4sePHkCNLnky5MuGehiSaWhRTsy7L/jAL0jyKszdeogGQdvvBkMGY8y49KvnyFqYTRS8hSmTwQm5KT3gO3Z0JdiJcomoDwPAuEb3hxEGVtGjoCSFDICVRxN480vZJzRJRt6Rj0kwkALL8LrVjkorhk2YbUo5cVHQAvVfJF0Tf0gXowxn0xHwEUpLFJcINVZIlyklygTiahLdKBAAMNVFqiZCgWyICJHLffIvAIogtlBzx0yAeGhcJhZ5glIkKJT0C3XqUwCAIjc8Nt2AkAEJISQruDTVAAcPRCICElwBZCf+L/gEYlHORrPDJgwD8N5xEwhnpSkkdHjKKiVx6yEp0XSpSCpMzoSIlJS520iCAWppCy4CC+OhjjtFc6UwAPkrk2yZWfljhOMfFWV2CTxoSqKAeDiVBhXxW4mMiB0qSwSQ2cuJjmocMJY6GgpQkDi2V4ncJDw46ORSNTECqJyUkYgrADQBkCgAOm9BZU3W1AIDeRUH2qaihmxBn0Z+qvCfsLcQiRImPukoyKQCFlNqgIIgO0NyiPrYJDnzPVTKeKifIIlyVmF3r32/fgZmkr7W6FgmyExnE6IqAQiciAEpuMi4AKhiwCAMsAMCpd/pa0q8lGGFkoSAafpfIwosWtUj/BaF4e2slRf06zwP/3XIAT/uawmQm9LZ7Iigp28tKykLtOAmiARkinAQ5VnABbLZ+sMgHKiay5iQOLJqoNhsAEK2/M/OaSMl7WkirIKUKEpxEI02k7SXBDQd1ItNK4oO8tj1LqNVnO13h1pIsMq2uJ5MNwA+RbAqALQI/HImuVVfiLEkAtCeIx4ks88yBB9IKbbyNiKB0JwJ10ze69ZhIVNNoPy0bhodiPQ/bk4TdqejYqi3I15H8LW3aVFeSBGaTA5Btd81QpzGQqFZNpSTUBR2KraBSgqjePJZU0r1iCmJr22mbiErSidwOL763qHqfcPv+R5rRR/PIudCZxKr8/yRMkg6ABzZX8l6RlbQGLCrdxzbiJvvB4yVQOo6GibFCWRK7/rox3v0ykT+EwcJoQlkZJ6izAeiJb2LgEwSTuEc8UywBXsEpSgtCRIG6pQdB8pNdJLQ0AQDIYABF2JXVCCAqpbHwOPfJEYBgU6p/GaIBHxREd8AmvBA9ThBT61WdLsEp0a2KP4bwka0WoYBK8C0z1elSbdYnm0jEiifTKtVvLmhDSnjMFo+ABa10ZYuhaax0AxGhJ3CTiOC00I3zyM364JMIJFUvEp+ZSPpgCBuElKpUPmrNH6s4OO85CQA2ABxMAKCx5dmPcBUxhuoAMDTsuCIkg4rEwoDVL1vB5v89mAyAiuwYKkykoAPy0piz0oRDR4pnSVacBdS4txpBkJJNkdTOwMZXPVXZq5aVWN4mb/ENFRSlTYtC3SnOJQgiBUBLoATASKIzRwWZShKbjOY0YTPMSdjQjruZJiXs6KzXmCQRcauRIUpADyMdIR6+O6UmWDkN9HRta0mohIyIVUBN5jI+8aFjJbozNCEtwIM4BI4hhra01Umia4mqDwyhU4kddcd3SkydPlVoCCUYTI/vcyFpbDQt9+XwmmrzUUIVdQn0tAqMezNEDwDwtzN2ahEycw/9BIoJ0ZmvO/2URCVpmh6BLg5/kHACQBNRnkRUS0iRXJrGmPQOwXkTGMH/o8QIkpgJiW2iX4GqRDgukchITKCbGRLEwmy6QFjWkZAnhdJpKGUIjQ1VEJN05cLCpjpclc2DAJxZpEJ6CImoC5iGoAHTNOFVTOQUrWP9USRiJ5CVWqKxp0inrDBRwkUqDB/o6ZsMIuEiAphUFGjtRNYMVIn/qOhvZZ1EbBOBKhuar5CWOORsZQegSRwxEu+wFQGI5aPYyaKbPmpErBpRpvkB8RLMBdg5DXFBSwgEps9tI2md6ImQaWK1odDeZEMxrUnyMHOsywSTlOTdTbB1EjntYios8B4RmUgWEqXcLuH7idTyzhPZQaoy0bWaGWVyTwOmEAFElCMRDS9hoGgT/09y6pwASIQesAlaNT/kAA10wDTg2FfeEME+bP0EM0cYMCXYyAgqEuTCFrYEhTvRTfn617GUmHEpMfEeGmnWt4cURIAt50NKiNeQRJGBKH2r4nNgNnmjMB+RbwsaJ5fiPbU0H5Y/MWXv6OZ7gAHvKsRc5YaQ+RRn3kWay8zmNrv5zXCOs5znTOc62/nOeM6znvfM5z77+c+ADrSgB03oQhv60IhOtKIXzehGO/rRkI60pCdN6Upb+tKYzrQ1lBNgn0AHsZmgjsxuKYqDEUvTl+6bjdTTNujMeMPI49cklgbJXkI4NjYKASVRzWu6igQAL7iUJFx5CeUcTEYYktmHKf8Kihf0+tmJyBsACsappt40RDuULQCaEItIKNltkQhirQ3RHlZPAmSI+MAFRvaKHECb1+OZJurCRb5MaEwgAnmvND0LgEd5tYQtoN67L429EtxxXgAaMJFVZJASWtWIJZ7fgA6U01Z29IcDJ3iRz/xATfzrt+oCAKowEsSg8aSuUDT3eTNe6bjZIsXbAhBiSS231g0Rt/5MhC1wkU9jIhyqgrgryyONPZam6tMVTcS4CTtdAnwjVjEATySnOt2C7Wnoj6bqkeD6PwAU1x4DNQSFBikJW3RtQ7yJxEy5jfVHL/1bAILAbnnLbEr91hAHWxA5msuw8aLIEDtSYNsPrWAgBgP9wV77BGzOnggHAGDZkRDxUHx295MDxUdNHvxjAgEAOw=="/>
58、
59、分析H2<sup>+</sup>的交换积分(b积分)<em>Hab</em>为负值的根据
60、
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发表于 2017-11-14 19:48:57
