易百教育 › 网院作业 › 西南大学网院17秋[0225]结构化学在线作业及答案

在线作业答案 发表于 2017-11-14 19:48:57

西南大学网院17秋[0225]结构化学在线作业及答案

0225
1、与结构基元相对应的是西南大学网院答案请咨询微信或QQ515224986

    素向量
    晶胞
    复格子
    点阵点
参考答案：点阵点；
2、杂化轨道是
    两个原子的原子轨道线性组合形成一组新的原子轨道
    一个原子的不同类型的原子轨道线性组合形成一组新的原子轨道
    两个分子的分子轨道线性组合形成一组新的分子轨道
    两个原子的原子轨道线性组合形成一组新的分子轨道
参考答案：一个原子的不同类型的原子轨道线性组合形成一组新的原子轨道；
3、晶体等于
    F.结构基元+点阵
    特征对称要素+结构基元
    晶胞+点阵
    特征对称要素+点阵
参考答案：F.结构基元+点阵；
4、若用电子束与中子束分别作衍射实验，得到大小相同的环纹，则说明二者
    A.动能相同
    动量相同
    速度相同
    质量相同
5、下列分子具有偶极矩，而不属于Cnv群的是
    H2C=CH2
    CH2Cl2
    NH3
    H2O2
6、杂化轨道不必满足下列哪一条性质
    E.杂化轨道必须是正交归一的
    每个轨道在杂化前后总成分保持不变
    杂化轨道必然是简并的轨道
    轨道杂化前后数目必须守恒
7、Li原子的3个电离能分别为I1=5.392eV,I2=75.638eV,I3=122.451eV。则Li原子1s电子的结合能是：
    -138.17eV
    -75.64eV
    -65.3eV
    -203.48eV
8、离子晶体中，负离子在正离子周围形成配位多面体。根据正负离子的半径比，可以判断正离子的配位数与配位多面体型式。下列判断正确的是：
    r+/r-=0.2正离子配位多面体为四面体
    r+/r-=0.3正离子配位多面体为三角形
    r+/r-=0.4正离子配位多面体为立方体
    r+/r-=0.5正离子配位多面体为八面体
9、考虑到电子的自旋，氢原子n=3的微观运动状态有多少种：
    3
    6
    9
    18
10、对于一维势箱中的粒子，下列说法错误的是：
    体系的基态能量为零
    波函数的节点数为n-1
    粒子在箱中动量的平均值为零
    粒子在箱中的运动满足不确定关系
11、提出实物粒子也有波粒二象性学的科学家是：
    德布罗意
    爱因斯坦
    海森堡
    狄拉克
12、分子轨道是
    原子轨道的线性组合
    分子中所有电子空间运动的状态函数
    分子中单电子运动的完全波函数
    分子中电子空间运动的轨道
13、根据宏观对称要素知道某晶体属D2d点群，由此判断此晶体属于()晶系
    D.立方
    正交
    单斜
    四方
14、Pauli原理的正确叙述为
    C.原子中每个电子的运动状态必须用四个量子数来描述
    同一原子中不可能有四个量子数完全相同的两个电子
    每个自旋-轨道最多只能容纳自旋方向相反的两个电子
    电子体系的空间波函数对于交换电子必须是反对称的
15、分子的三重态意味着分子中
    B.有三对未成对电子
    有两个自旋相同的未成对电子
    有一个未成对电子
    有两个自旋相反的未成对电子
16、O2的键长小于O2^?的键长
    A.√
    B.×
17、凡是成键轨道都具有中心对称性
    A.√
    B.×
18、通过解氢原子的薛定谔方程，可得到<em>n，l，m</em>和<em>ms</em>四个量子数
    A.√
    B.×
19、用HMO法处理共轭分子时，其久期行列式中，主对角线上积分元的数值为，与主对角线上的相连的积分元数值为，其他的积分元为零
    A.√
    B.×
20、立方最密堆积型金属和六方最密堆积金属的堆积系数相等，晶胞内原子数、八面体空隙数、四面体空隙数的比值均为1:1:2
    A.√
    B.×
21、氢原子的2p轨道能级比2s轨道能级高
    A.√
    B.×
22、正当格子一定是素格子
    A.√
    B.×
23、电子自旋量子数<em>s</em>=±1/2
    A.√
    B.×
24、中心原子采用dsp²杂化方式，其空间构型为四面体
    A.√
    B.×
25、立方晶系的空间点阵形式有cP,cI,cF与cR。
    A.√
    B.×
26、晶体中对称轴的轴次只能是1,2,3,4,6。
    A.√
    B.×
27、甲烷分子有对称中心。
    A.√
    B.×
28、仅由非极性键构成的分子不一定是非极性分子
    A.√
    B.×
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39、按分子轨道理论写出NF，NF⁺，NF^?基态时的电子组态，说明他们的不成对电子数和磁性（提示：按照类似O2的能级排）
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41、在极性分子AB中的一个分子轨道上运动的电子，在A原子的f</em>A原子轨道上出现的概率为80%，B原子的f</em>B原子轨道上出现的概率为20%，写出该分子轨道波函数。
42、写出N2基态时的价层电子组态，并解N2的键长(109.8pm)特别短、键能(942kJ·mol^-1)特别大的原因。
43、
44、写出NF⁺的价电子组态、键级和磁性。
45、
46、<imgwidth="554"height="42"src="data:image/png;base64,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"/>
47、链型共轭分子<imgwidth="197"height="23"src="data:image/png;base64,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"/>的长波方向460nm处出现第一个强吸收峰，试按一维势模型估算其长度。
48、<imgwidth="554"height="42"src="data:image/png;base64,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"/>
49、在LCAO-MO方法中，各原子轨道对分子轨道的贡献可由哪个决定：-----------------()(A)组合系数ij(B)(ij)2</sup>(C)(ij)1/2</sup>(D)(ij)-1/2(B)
50、请通过计算说明，用氢原子从第六激发态跃到基态所产生的光子照射长度为1120pm的线型分子H2CCHCHCHCHCHCH2，该分子能否产生吸收光谱？若能，计算谱线的最长波长；若不能，请提出将不能变为可能的思路。
51、写出CN-</sup>的价电子组态及键级
52、什么叫分子轨道？按量子力学基本原理做了哪些近似以后才有分子轨道的概念？这些近似的根据是什么？
53、<imgwidth="554"height="42"src="data:image/png;base64,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"/>
54、对于氢原子：（a）分别计算从第一激发态和第六激发态跃迁到基态所产生的光谱线的波长，说明这些谱线所属的线系及所处的光谱范围。（b）上述两谱线产生的光子能否使：（i）处于基态的另一氢原子电离？（ii）金属铜中的原子电离？（铜的功函数(c)若上述两谱线所产生的光子能使铜晶体的电子电离，请计算从铜晶体表面射出的光电子的德布罗意波的波长
55、<imgwidth="554"height="83"src="data:image/png;base64,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"/>
56、试述由原子轨道有效地形成分子轨道的条件。
57、<imgwidth="554"height="104"src="data:image/png;base64,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"/>
58、
59、分析H2⁺的交换积分(b积分)<em>Hab</em>为负值的根据
60、
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